José Ureña (0-7) surrendered seven runs — four earned — and four hits in four-plus innings.
Chicago had a 4-1 lead before Ureña's throwing error helped Arizona score two runs in the third. The Diamondbacks then went ahead to stay with six runs in the fifth.
With Geraldo Perdomo aboard after a leadoff walk, Corbin Carroll hit a grounder to second. Elvis Andrus threw to Tim Anderson looking for the force at second base, but the shortstop was charged with an error after a replay challenge showed he was off the bag when he caught the ball. Ureña departed after Tommy Pham's bases-loaded walk tied it at 4. Walker then greeted Yohan Ramirez with his second triple of the season. Alek Thomas hit an RBI single in his hometown, and Gabriel Moreno made it 9-4 with a sacrifice fly.
Ketel Marte connected for his 25th homer in the eighth, and Perdomo hit a two-run triple in Arizona's three-run ninth.White Sox: OF Luis Robert Jr. was placed on the 10-day injured list, ending his career-best season. OF Tyler Naquin was brought up from Triple-A Charlotte, and RHP Jimmy Lambert was transferred to the 60-day IL.Arizona right-hander Brandon Pfaadt takes the mound Wednesday.
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