Thermally induced orderly alignment of porphyrin photoactive motifs in metal-organic frameworks

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Thermally induced orderly alignment of porphyrin photoactive motifs in metal-organic frameworks
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Professor Shi Weiqun's group from the Institute of High Energy Physics of the Chinese Academy of Sciences has made progress in the application of metal-organic frameworks (MOFs) in the field of photocatalytic CO2 reduction. The study was published in Journal of the American Chemical Society.

Professor Shi Weiqun's group from the Institute of High Energy Physics of the Chinese Academy of Sciences has made progress in the application of metal-organic frameworks in the field of photocatalytic COThe researchers constructed the MOF material IHEP-21 with the actinide metal thorium as the node and the functional organic ligand porphyrin, and proposed to utilize a thermally induced strategy to obtain the MOF materials IHEP-22 and IHEP-23 via a two-step...

. The large ionic radius and high coordination number of thorium give IHEP-21 more structural variability, which is conducive to the thermally induced multi-step crystal transformation process of actinide-porphyrin MOFs.

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